Anti-cancer activity of hierarchical ZSM-5 zeolites synthesized from rice-based waste materials

Preparing hierarchical nanoporous ZSM-5 zeolite via post-synthetic modification of zeolite synthesized from bagasse and its application for removal of Pb2+

In this study, hierarchical H-ZSM-5 zeolite is prepared via post-synthetic modification of parent H-ZSM-5 zeolite (Si/Al=35) synthesized from bagasse (BGA) as silica source using desilication with alkaline treatment (AT). For optimizing the effective parameters on desilication, Taguchi method was utilized. Cultivated BGA in the south of the Caspian Sea (Mazandaran province, Iran) is applied for...

Adsorption of carbon monoxide in H-ZSM-5 and Li-ZSM-5 zeolites: an embedded ab initio cluster study

The absorption of carbon monoxide with H-ZSM-5 and metal-substituted Li-ZSM-5 zeolites has been investigated by Ž . using both cluster and embedded cluster approaches at the HFr6–31G d,p level of theory. For the H-ZSM-5 zeolite, the binding energy of CO on a 3T quantum cluster is predicted to be 2.25 kcalrmol for the C-bound complex. The O-bound complex was found to be less stable by about 0.84...

Antibacterial activity of materials synthesized from clay minerals

The antibacterial activity of silver and cationic surfactant modified smectites from North Patagonian, Argentina, were tested in growth inhibition of Escherichia coli bacteria by the test of susceptibility on solid medium. The exchange reactions were carried out using Ag and hexadecyltrimethylammonium (HDTMA) cations in larger amounts than those conventionally required to form monolayer on the ...

Tailoring ZSM-5 Zeolites for the Fast Pyrolysis of Biomass to Aromatic Hydrocarbons.

The production of aromatic hydrocarbons from cellulose by zeolite-catalyzed fast pyrolysis involves a complex reaction network sensitive to the zeolite structure, crystallinity, elemental composition, porosity, and acidity. The interplay of these parameters under the reaction conditions represents a major roadblock that has hampered significant improvement in catalyst design for over a decade. ...

Crystallization of Sub-Micrometer Sized ZSM-5 Zeolites in SDA-Free Systems